List of works - Apparao Draksharapu

Novel artificial metalloenzymes by in vivo incorporation of metal-binding unnatural amino acids.

scientific article published on 9 October 2014

Ligand exchange and spin state equilibria of Fe(II)(N4Py) and related complexes in aqueous media

scientific article published on 23 December 2011

Reactivity of a Nickel(II) Bis(amidate) Complex with meta-Chloroperbenzoic Acid: Formation of a Potent Oxidizing Species

scientific article published on 25 August 2015

Identification and spectroscopic characterization of nonheme iron(III) hypochlorite intermediates.

scientific article published on 6 February 2015

Characterisation of the interactions between substrate, copper(II) complex and DNA and their role in rate acceleration in DNA-based asymmetric catalysis

scientific article published in February 2015

Rapid Hydrogen and Oxygen Atom Transfer by a High-Valent Nickel-Oxygen Species

scientific article published on 6 September 2016

Spectroscopic Analyses on Reaction Intermediates Formed during Chlorination of Alkanes with NaOCl Catalyzed by a Nickel Complex

scientific article published on 5 November 2015

Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units

scientific article

Binding of copper(II) polypyridyl complexes to DNA and consequences for DNA-based asymmetric catalysis

scientific article published on February 2015

Photo-induced oxidation of [Fe(II)(N4Py)CH3CN] and related complexes.

scientific article published in November 2012

Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex

scientific article published on 5 June 2017

Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

scientific article published in February 2014

Conflicting Role of Water in the Activation of H2O2 and the Formation and Reactivity of Non-Heme Fe(III)-OOH and Fe(III)-O-Fe(III) Complexes at Room Temperature

scientific article published on 13 April 2016

Direct photochemical activation of non-heme Fe(iv)[double bond, length as m-dash]O complexes

scientific article

Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-oxo Intermediate

scientific article published on 20 February 2018

Off-line reaction monitoring of the oxidation of alkenes in water using drop coating deposition Raman (DCDR) spectroscopy.

scientific article

Reinvestigating 2,5-di(pyridin-2-yl)pyrazine ruthenium complexes: selective deuteration and Raman spectroscopy as tools to probe ground and excited-state electronic structure in homo- and heterobimetallic complexes

scientific article published on 18 August 2011

Sc (or HClO) Activation of a Nonheme Fe-OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene

scientific article published on 17 April 2018

Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III).

scientific article published on 9 June 2017

Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds.

scientific article

Crystallographic Evidence for a Sterically Induced Ferryl Tilt in a Non-Heme Oxoiron(IV) Complex that Makes it a Better Oxidant

scientific article published on 28 June 2018

A Non-Heme Iron Photocatalyst for Light-Driven Aerobic Oxidation of Methanol

scientific article published on 15 January 2018

H2O2 Oxidation by FeIII–OOH Intermediates and Its Effect on Catalytic Efficiency

scientific article published on 6 September 2018

Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases

scientific article published on 7 December 2017

On the Lewis Acidity of the Oxoiron(IV) Unit in a Tetramethylcyclam Complex

scientific article published on 2 December 2017

NMR Reveals That a Highly Reactive Nonheme FeIV =O Complex Retains Its Six-Coordinate Geometry and S=1 State in Solution

scientific article published on 27 June 2019

Sc3+-Promoted O-O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O2 to Generate a Complex with an FeIV2(μ-O)2 Core

scientific article published on 19 February 2020

Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III)

scholarly article by Apparao Draksharapu et al published 27 June 2017 in Angewandte Chemie

Acid pKa Dependence in O-O Bond Heterolysis of a Nonheme FeIII-OOH Intermediate To Form a Potent FeV═O Oxidant with Heme Compound I-Like Reactivity

scientific article published on 26 September 2019

Facile Conversion of syn -[FeIV (O)(TMC)]2+ into the anti Isomer via Meunier's Oxo-Hydroxo Tautomerism Mechanism

scientific article published on 17 January 2019

An Electrochemical and Raman Spectroscopy Study of the Surface Behaviour of Mononuclear Ruthenium and Osmium Polypyridyl Complexes Based on Pyridyl- and Thiophene-Based Linkers

scholarly article by Yvonne Halpin et al published 17 June 2013 in European Journal of Inorganic Chemistry

Spectroscopic characterization of a Ru( iii )-OCl intermediate: a structural mimic of haloperoxidase enzymes

scientific article published in 2022

Facile Conversion of syn‐[FeIV(O)(TMC)]2+ into the anti Isomer via Meunier's Oxo–Hydroxo Tautomerism Mechanism

Spectroscopy, photophysics and structural dynamics in metal‐centred species, some recent investigations: from spin‐crossover complexes and oxygen activation to photocatalysis

article

A Non-Heme Iron Photocatalyst for Light-Driven Aerobic Oxidation of Methanol

Crystallographic Evidence for a Sterically Induced Ferryl Tilt in a Non-Heme Oxoiron(IV) Complex that Makes it a Better Oxidant

Spectroscopic and Reactivity Comparisons between Nonheme Oxoiron(IV) and Oxoiron(V) Species Bearing the Same Ancillary Ligand

scientific article published on 11 September 2019

Unexpected reversible pyrazine based methylation in a Ru(ii) complex bearing a pyrazin-2′-yl-1,2,4-triazolato ligand and its effect on acid/base and photophysical properties

scientific article published on 04 December 2012

List of works by Apparao Draksharapu

Novel artificial metalloenzymes by in vivo incorporation of metal-binding unnatural amino acids.

Ligand exchange and spin state equilibria of Fe(II)(N4Py) and related complexes in aqueous media

Reactivity of a Nickel(II) Bis(amidate) Complex with meta-Chloroperbenzoic Acid: Formation of a Potent Oxidizing Species

Identification and spectroscopic characterization of nonheme iron(III) hypochlorite intermediates.

Characterisation of the interactions between substrate, copper(II) complex and DNA and their role in rate acceleration in DNA-based asymmetric catalysis

Rapid Hydrogen and Oxygen Atom Transfer by a High-Valent Nickel-Oxygen Species

Spectroscopic Analyses on Reaction Intermediates Formed during Chlorination of Alkanes with NaOCl Catalyzed by a Nickel Complex

Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units

Binding of copper(II) polypyridyl complexes to DNA and consequences for DNA-based asymmetric catalysis

Photo-induced oxidation of [Fe(II)(N4Py)CH3CN] and related complexes.

Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex

Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

Conflicting Role of Water in the Activation of H2O2 and the Formation and Reactivity of Non-Heme Fe(III)-OOH and Fe(III)-O-Fe(III) Complexes at Room Temperature

Direct photochemical activation of non-heme Fe(iv)[double bond, length as m-dash]O complexes

Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-oxo Intermediate

Off-line reaction monitoring of the oxidation of alkenes in water using drop coating deposition Raman (DCDR) spectroscopy.

Reinvestigating 2,5-di(pyridin-2-yl)pyrazine ruthenium complexes: selective deuteration and Raman spectroscopy as tools to probe ground and excited-state electronic structure in homo- and heterobimetallic complexes

Sc (or HClO) Activation of a Nonheme Fe-OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene

Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III).

Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds.

Crystallographic Evidence for a Sterically Induced Ferryl Tilt in a Non-Heme Oxoiron(IV) Complex that Makes it a Better Oxidant

A Non-Heme Iron Photocatalyst for Light-Driven Aerobic Oxidation of Methanol

H2O2 Oxidation by FeIII–OOH Intermediates and Its Effect on Catalytic Efficiency

Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases

On the Lewis Acidity of the Oxoiron(IV) Unit in a Tetramethylcyclam Complex

NMR Reveals That a Highly Reactive Nonheme FeIV =O Complex Retains Its Six-Coordinate Geometry and S=1 State in Solution

Sc3+-Promoted O-O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O2 to Generate a Complex with an FeIV2(μ-O)2 Core

Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III)

Acid pKa Dependence in O-O Bond Heterolysis of a Nonheme FeIII-OOH Intermediate To Form a Potent FeV═O Oxidant with Heme Compound I-Like Reactivity

Facile Conversion of syn -[FeIV (O)(TMC)]2+ into the anti Isomer via Meunier's Oxo-Hydroxo Tautomerism Mechanism

An Electrochemical and Raman Spectroscopy Study of the Surface Behaviour of Mononuclear Ruthenium and Osmium Polypyridyl Complexes Based on Pyridyl- and Thiophene-Based Linkers

Spectroscopic characterization of a Ru( iii )-OCl intermediate: a structural mimic of haloperoxidase enzymes

Facile Conversion of syn‐[FeIV(O)(TMC)]2+ into the anti Isomer via Meunier's Oxo–Hydroxo Tautomerism Mechanism

Spectroscopy, photophysics and structural dynamics in metal‐centred species, some recent investigations: from spin‐crossover complexes and oxygen activation to photocatalysis

A Non-Heme Iron Photocatalyst for Light-Driven Aerobic Oxidation of Methanol

Crystallographic Evidence for a Sterically Induced Ferryl Tilt in a Non-Heme Oxoiron(IV) Complex that Makes it a Better Oxidant

Spectroscopic and Reactivity Comparisons between Nonheme Oxoiron(IV) and Oxoiron(V) Species Bearing the Same Ancillary Ligand

Unexpected reversible pyrazine based methylation in a Ru(ii) complex bearing a pyrazin-2′-yl-1,2,4-triazolato ligand and its effect on acid/base and photophysical properties

Dinuclear compounds without a metal–metal bond. Dirhodium(III,III) carboxamidates